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Polyurethanes (PUs) are extremely versatile materials used across different industries. Traditionally, they are synthesized by reacting polyols and isocyanates, both of which are petroleum-derived reagents. In response to the demand for more eco-friendly materials, research has increasingly focused on developing new routes for PU synthesis using renewable feedstocks. While substituting isocyanates remains a greater challenge, replacing fossil-based polyols with bio-based alternatives is now a promising strategy. This review explores the main natural sources and their transformations into bio-polyols, the incorporation of bio-fillers into PU formulations, and the production of non-isocyanate polyurethanes (NIPUs). Additionally, the study summarizes the growing body of research that has reported successful outcomes using bio-polyols in PU foams for distinct applications.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12108712 | PMC |
http://dx.doi.org/10.3390/biom15050680 | DOI Listing |
RSC Adv
August 2025
Department of Chemistry, Faculty of Forestry and Wood Technology, Poznan University of Life Sciences Wojska Polskiego 28 60-637 Poznań Poland.
This study aims to evaluate the application potential of unrefined vegetable oils derived from three plant species- (), (), and rapeseed ( L. var. )-as renewable raw materials for the synthesis of bio-based polyurethane foams.
View Article and Find Full Text PDFPolymers (Basel)
August 2025
Department of Robotics and Manufacturing Systems, Faculty of Industrial Engineering and Robotics, National University of Science and Technology POLITEHNICA Bucharest, 060042 Bucharest, Romania.
This systematic literature review explores recent advancements in polymer-based composite materials designed for thermal insulation in automotive applications, with a particular focus on sustainability, performance optimization, and scalability. The methodology follows PRISMA 2020 guidelines and includes a comprehensive bibliometric and thematic analysis of 229 peer-reviewed articles published over the past 15 years across major databases (Scopus, Web of Science, ScienceDirect, MDPI). The findings are structured around four central research questions addressing (1) the functional role of insulation in automotive systems; (2) criteria for selecting suitable polymer systems; (3) optimization strategies involving nanostructuring, self-healing, and additive manufacturing; and (4) future research directions involving smart polymers, bioinspired architectures, and AI-driven design.
View Article and Find Full Text PDFMaterials (Basel)
August 2025
Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, 26 Hexing Road, Harbin 150040, China.
In this study, alkali-treated wood flour/dynamic polyurethane composites were successfully prepared through a solvent-free one-pot method and in situ polymerization. The effects of the alkaline treatment process, changes in the flexible long-chain content in the dynamic polyurethane system, and the wood flour filling amount on the interface's bonding, mechanical, and reprocessing properties were investigated. Partial removal of lignin and hemicellulose from the alkali-treated wood flour enhanced rigidity and improved interface bonding and mechanical strength when combined with dynamic polyurethane.
View Article and Find Full Text PDFPolymers (Basel)
July 2025
MOE Key Laboratory of High Performance Polymer Materials and Technology, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.
Bio-based polyurethane asphalt binder (PUAB) derived from castor oil (CO) is environmentally friendly and exhibits extended allowable construction time. However, CO imparts inherently poor mechanical performance to bio-based PUAB. To address this limitation, attapulgite (ATT) with fibrous nanostructures was incorporated.
View Article and Find Full Text PDFInt J Biol Macromol
September 2025
Key Laboratory of Industrial Biocatalysis, Ministry of Education, Tsinghua University, Beijing 100084, China; Department of Chemical Engineering, Tsinghua University, Beijing 100084, China. Electronic address:
Polyether polyols (PEPs) are crucial raw materials for synthesizing polyurethanes (PUs). Commercial PEPs are predominantly classified as petroleum-based or bio-based. This review comprehensively summarizes recent advances in the synthesis of representative bio-based PEPs, focusing on biomass-derived and bio-based feedstocks.
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