Palladium Hydride Anchored on SrTiO with Efficient Charge Separation and Surface Reaction Kinetics for Enhanced Photocatalytic Overall Water Splitting.

Cocatalyst engineering is critical for advancing photocatalysis, as it suppresses charge carrier recombination, promotes interfacial electron/hole extraction, and serves as active sites for redox reactions. However, the incompatibility existing between the cocatalyst and host photocatalyst, along with its intrinsic properties of active sites, limits further improvements in the charge separation, surface reaction kinetics, and overall performance. Herein, we introduce palladium hydrides (PdH) as an efficient cocatalyst on SrTiO (STO) for photocatalytic overall water splitting, owing to their similar lattice parameters. The constructed PdH/STO demonstrates a remarkable 6.4-fold enhancement in hydrogen evolution compared to the Pd/STO control, reaching a rate of 5 mmol·g·h at a stoichiometric H/O ratio of 2:1. Structural characterizations and theoretical analyses prove that the formed PdH sites feature the advantages of accelerated electron extraction and modulated hydrogen adsorption energies for hydrogen evolution; femtosecond transient absorption spectroscopy further reveals prolonged charge carrier lifetime and improved charge transfer efficiency.