Incorporation of Cu(I) Sites into Zeolite via a Controllable Reduction Strategy for Ethylene/Ethane Separation.

The development of effective adsorbents for efficient separation of ethylene (CH) and ethane (CH) is crucial for the petrochemical sector, yet this is still difficult because of their comparable molecule sizes and physical characteristics. Cu(I) could generate π-complexes with molecules containing unsaturated bonds, enabling Cu(I)-based adsorbents to selectively and efficiently separate CH from CH. However, the traditional autoreduction method typically requires extreme temperatures (≥700 °C) to convert Cu(II) to Cu(I), leading to high energy consumption. In this study, we present a controllable reduction strategy that employs methanol as the reductant to efficiently and controllably convert Cu(II) in Y zeolite to Cu(I). With this approach, Cu(I) sites could be formed under a modest temperature of 200 °C. Due to the generated Cu(I) sites, the CH uptake for Cu(I)-Y reaches 3.85 mmol/g and the CH/CH selectivity is 19.21. This performance surpasses those of benchmark adsorbents, including CuX (2.31 mmol/g, 1.06), Cu(I)-doped mesoporous carbon MC-Cu-2 (1.94 mmol/g, 4.00), and Cu@MIL-101 (2.46 mmol/g, 14.00).