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Article Abstract
The control of the sequential self-assembly processes of highly entangled (AgL) (n=2,4,6,8) and AgL coordination polyhedra using side-chain effects was studied via the introduction of linear or branched side chains into the tripodal ligands. In addition to changes in the intermediate polyhedral species affording the multi- pathway process, disruption of the kinetic control of the sequential self-assembly was observed, thus demonstrating the utility of steric control for the construction of 3D-entangled molecular materials on the 5 nm scale with high molecular complexity.
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| http://dx.doi.org/10.1002/asia.202401378 | DOI Listing |
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