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Article Abstract
A divergent total synthesis of bioactive, naturally occurring decanolides, pinolidoxin and bellidisin C, was accomplished by taking advantage of chiral templates -ribose and -malic acid. In particular, bellidisin C, which is the first total synthesis so far, was achieved through a cascade reaction of reductive elimination and nucleophilic addition in a one-pot process and a sodium-alkoxide-promoted intramolecular lactonization as the key steps.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11643441 | PMC |
| http://dx.doi.org/10.3390/molecules29235500 | DOI Listing |
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