Long-term soil remediation using layered double hydroxides: Field evidence for simultaneous immobilization of both cations and oxyanions.

Layered double hydroxides (LDHs) have great potential for immobilizing potentially toxic elements in soil. Nevertheless, their practical effectiveness under field conditions remains largely unknown. In this study, we conducted a 2.5-year field trial using pristine Mg-Al LDHs, Ca-Al LDHs, and iron (Fe)-modified LDHs to simultaneously immobilize both oxyanions (including As and Sb) and cations (including Cd and Pb) in historically contaminated soil affected by mining activities since the 1950s. The immobilization performance of LDHs was examined using various batch tests, including water and DTPA extraction, and by measuring metal(loid) concentrations in Coriandrum sativum (coriander). We found that both pristine and Fe-modified LDHs showed promising initial immobilization performance 7 days after application, achieving significant reductions in DTPA-extractable concentrations of As, Sb, Cd, and Pb by 45.6%-68.3%, 55.4%-94.2%, 11.2%-50.9%, and 62.9%-64.9%, respectively, compared to the control soil without amendment. Notably, pristine LDHs showed diminished immobilization performance in the long term, while Fe-modified LDHs exhibited long-term stability over 2.5 years. A conditional probability-based model was used to depict long-term metal(loid) leaching characteristics in LDH-amended soils. Temporal changes in metal(loid) concentrations in the aboveground edible parts (namely, stems and leaves) of coriander corroborated well with DTPA extraction results. Coriander grown in Fe-modified LDH-amended soils had much lower metal(loid) concentrations compared to those grown in pristine LDH-amended soils. As a result, reductions of 35.1%-42.2% for As, 54.4%-66.2% for Sb, 8.5%-22.8% for Cd, and 56.0%-62.7% for Pb concentrations in coriander were still observed 2.5 years after soil amendment with Fe-modified LDHs. To the best of our knowledge, this is the first field-based evidence using LDHs to simultaneously stabilize both cations and oxyanions in soil. The findings support the potential of LDHs for long-term immobilization of metal(loid)s in soil.