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We study the scaling behavior of the Rényi entanglement entropy with smooth boundaries at the putative deconfined critical point separating the Néel antiferromagnetic and valence-bond-solid states of the two-dimensional J-Q_{3} model. We observe a subleading logarithmic term with a coefficient indicating the presence of four Goldstone modes, signifying the presence of an SO(5) symmetry at the transition point, which spontaneously breaks into an O(4) symmetry in the thermodynamic limit. This result supports the conjecture that an SO(5) symmetry emerges at the transition point, but reveals the transition to be weakly first-order. We demonstrate, through this Letter, a novel approach to detect emergent continuous symmetry and, more importantly, identify weakly first-order phase transitions efficiently, which have been notoriously challenging for conventional methods.
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http://dx.doi.org/10.1103/PhysRevLett.133.100402 | DOI Listing |
Phys Rev Lett
August 2025
Weizmann Institute of Science, Department of Condensed Matter Physics, Rehovot 7610001, Israel.
We address the problem of identifying a 2+1D topologically ordered phase using measurements on the ground-state wave function. For nonchiral topological order, we describe a series of bulk multipartite entanglement measures that extract the invariants ∑_{a} d_{a}^{2}θ_{a}^{r} for any r≥2, where d_{a} and θ_{a} are the quantum dimension and topological spin of an anyon a, respectively. These invariants are obtained as expectation values of permutation operators between 2r replicas of the wave function, applying different permutations on four distinct regions of the plane.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Center for Advanced Structural Materials, State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China.
Increasing evidences show the significance of low melting entropy in glass formation of substances. Our previous studies have uncovered the strong dependence between melting entropy in the eutectic mixtures and mixing enthalpy, which has been serving as an important reference for glass formation, showing that negative mixing enthalpy largely reduces the melting entropy. In this paper, we focused on the question as to how melting entropy is associated with another classical glass formation criterion of molecule/atom size difference of components.
View Article and Find Full Text PDFJ Phys Chem A
September 2025
Dipartimento di Scienze Fisiche e Chimiche, Università degli Studi dell'Aquila, Coppito, L'Aquila 67100, Italy.
In recent years Quantum Computing prominently entered in the field of Computational Chemistry, importing and transforming computational methods and ideas originally developed within other disciplines, such as Physics, Mathematics and Computer Science into algorithms able to estimate quantum properties of atoms and molecules on present and future quantum devices. An important role in this contamination process is attributed to Quantum Information techniques, having the 2-fold role of contributing to the analysis of electron correlation and entanglements and guiding the construction of wave function variational ansatzes for the Variational Quantum Eigensolver technique. This paper introduces the tool SparQ (Sparse Quantum state analysis), designed to efficiently compute fundamental quantum information theory observables on post-Hartree-Fock wave functions sparse in their definition space.
View Article and Find Full Text PDFEntropy (Basel)
August 2025
Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90950, Riyadh 11623, Saudi Arabia.
In this work, we investigate the quantum coherence and purity in hydrogen atoms under dissipative dynamics, with a focus on the hyperfine structure states arising from the electron-proton spin interaction. Using the Lindblad master equation, we model the time evolution of the density matrix of the system, incorporating both the unitary dynamics driven by the hyperfine Hamiltonian and the dissipative effects due to environmental interactions. Quantum coherence is quantified using the L1 norm and relative entropy measures, while purity is assessed via von Neumann entropy, for initial states, including a maximally entangled Bell state and a separable state.
View Article and Find Full Text PDFEntropy (Basel)
August 2025
Research Center for Astronomy and Applied Mathematics of the Academy of Athens, Soranou Efessiou 4, GR-11527 Athens, Greece.
We study in detail the critical points of Bohmian flow, both in the inertial frame of reference (Y-points) and in the frames centered at the moving nodal points of the guiding wavefunction (X-points), and analyze their role in the onset of chaos in a system of two entangled qubits. We find the distances between these critical points and a moving Bohmian particle at varying levels of entanglement, with particular emphasis on the times at which chaos arises. Then, we find why some trajectories are ordered, without any chaos.
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