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Converting waste heat from solar radiation and industrial processes into useable electricity remains a challenge due to limitations of traditional thermoelectrics. Ionic thermoelectric (i-TE) materials offer a compelling alternative to traditional thermoelectrics due to their excellent ionic thermopower, low thermal conductivity, and abundant material options. This review categorizes i-TE materials into thermally diffusive and thermogalvanic types, with an emphasis on the former due to its superior thermopower. This review also highlights the i-TE materials for creating ionic thermoelectric supercapacitors (ITESCs) that can generate significantly higher voltages from low-grade heat sources compared to conventional technologies. Additionally, it explores thermogalvanic cells and combined devices, discussing key optimization parameters and theoretical modeling approaches for maximizing material and device performance. Future directions aim to enhance i-TE material performance and address low energy density challenges for flexible and wearable applications. Herein, the cutting-edge of i-TE materials are comprehensively outlined, empowering researchers to develop next-generation waste heat harvesting technologies for a more sustainable future.
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http://dx.doi.org/10.1039/d4sc04158e | DOI Listing |
Adv Mater
August 2025
State Key Laboratory for Reliability and Intelligence of Electrical Equipment, Engineering Research Center of Ministry of Education for Intelligent Rehabilitation Device and Detection Technology, Hebei Key Laboratory of Smart Sensing and Human-Robot Interaction, School of Mechanical Engineering, Heb
Ionic thermoelectric (i-TE) materials show promise for flexible energy harvesting and self-powered sensing due to their high ionic Seebeck coefficients (S). However, achieving both high thermoelectric performance and mechanical stretchability, especially in n-type systems, remains a critical challenge. Herein, a poly(vinyl alcohol) (PVA)-based n-type i-TE hydrogel is presented that exhibits both large negative S (-38.
View Article and Find Full Text PDFNano Lett
August 2025
Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Engineering Mechanics, Tsinghua University, 100084 Beijing, China.
While ionic thermoelectric (i-TE) materials can exhibit high thermopower, most of them rely on the addition of a large amount of ionic liquids (IL). This study demonstrates significant improvements in the thermopower of ionogels composed of poly(vinylidene fluoride--hexafluoropropylene) (PVDF-HFP) and 1-ethyl-3-methylimidazolium chloride (EMIM:Cl) through the asymmetric doping of sodium chloride (NaCl). This improvement results from the coupling of the preintroduced ion concentration difference and temperature difference, which reduces the cation migration barrier in the direction of thermal diffusion, leading to significantly enhanced performance compared to symmetric doping.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2025
School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, China.
Ionic thermoelectric (i-TE) hydrogel, combined with intrinsic softness, conductivity, and thermoelectricity, is a highly promising candidate for flexible thermoelectric materials to directly harvest low-grade thermal energy from the environment and the human body. However, efficiently converting heat into electricity without compromising structural robustness under extreme mechanical conditions is of great significance but still challenging. Herein, we prepared a poly(vinyl alcohol) (PVA)/sodium alginate (SA)/NaCl/Fe(CN) (PSNF) hydrogel with superior mechanical robustness and thermoelectricity, utilizing the combination of a dual thermoelectric effect by the freeze/thaw method and the Hofmeister effect.
View Article and Find Full Text PDFNanomicro Lett
March 2025
School of Integrated Circuits and Electronics, Beijing Institute of Technology, Beijing, 100081, People's Republic of China.
Thermoelectric technology that utilizes thermodynamic effects to convert thermal energy into electrical energy has greatly expanded wearable health monitoring, personalized detecting, and communicating applications. Encouragingly, thermoelectric technology assisted by artificial intelligence exerts great development potential in wearable electronic devices that rely on the self-sustainable operation of human body heat. Ionic thermoelectric (i-TE) devices that possess high Seebeck coefficients and a constant and stable electrical output are expected to achieve an effective conversation of thermal energy harvesting.
View Article and Find Full Text PDFSmall
March 2025
State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, China.
Ionogels are widely studied as promising ionic thermoelectric (i-TE) materials to harvest low-grade waste heat into electrical energy due to their huge thermopower and good ionic conductivity, providing a feasible way to sustainable development. Herein, a p-type i-TE cellulose ionogel (CIG) based on Soret effect is prepared by dissolving cellulose in an ionic liquid (IL) and subsequent water-absorbing induced gelation. Its morphological structure and IL distribution are intuitively investigated through cryo-focused ion beam-scanning electron microscope.
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