Dynamic negative allosteric effect: regulation of catalysis multicomponent rotor speed.

Chem Commun (Camb)

Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Technology, University of Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany.

Published: July 2024


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Article Abstract

Nanorotor R1 (420 kHz) was assembled from five components utilizing three orthogonal interactions. Post-modification at the distal position generated the advanced six component rotor R2 (45 kHz). The decrease in R2 speed leads to the inhibition of a three-component reaction by reducing catalyst release.

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http://dx.doi.org/10.1039/d4cc02144dDOI Listing

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