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Article Abstract
Rh(III)-catalyzed direct oxidative C-H/C-H cross-coupling between -pyrimidylindoles and β-ketoesters is presented. Easily available β-ketoesters are used as an alkylating agent for the facile construction of all-carbon quaternary centers under mild conditions. The ester group in the product can undergo decarboxylation or decarboxylative amination.
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| http://dx.doi.org/10.1021/acs.orglett.4c01631 | DOI Listing |
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Rhodium(III)-Catalyzed Oxidative Cross-Coupling of -Pyrimidylindoles with Cyclic β-Keto Esters for Accessing All-Carbon Quaternary Centers.
Org Lett
June 2024
Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao, 266237, P. R. China.
Rh(III)-catalyzed direct oxidative C-H/C-H cross-coupling between -pyrimidylindoles and β-ketoesters is presented. Easily available β-ketoesters are used as an alkylating agent for the facile construction of all-carbon quaternary centers under mild conditions. The ester group in the product can undergo decarboxylation or decarboxylative amination.
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