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Rhodium-Catalyzed Tandem Asymmetric Allylic Decarboxylative Addition and Cyclization of Vinylethylene Carbonates with -Nosylimines. | LitMetric
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Rhodium-Catalyzed Tandem Asymmetric Allylic Decarboxylative Addition and Cyclization of Vinylethylene Carbonates with -Nosylimines.

Xiao-Lin Wang , Hai-Bin Jiang , Sheng-Cai Zheng , Xiao-Ming Zhao

Molecules

School of Chemical Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, China.

Published: February 2024

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Article Abstract

A enantioselective tandem transformation, concerning asymmetric allylic decarboxylative addition and cyclization of -nosylimines with vinylethylene carbonates (VECs), in the presence of [Rh(CH)Cl], chiral sulfoxide--olefin tridentate ligand has been developed. The reaction of VECs with various substituted -nosylimines proceeded smoothly under mild conditions, providing highly functionalized oxazolidine frameworks in good to high yields with good to excellent enantioselectivity.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10934018PMC
http://dx.doi.org/10.3390/molecules29051019DOI Listing

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