Catalytic utility of PNN-based Mn pincer complexes in the synthesis of quinolines and transfer hydrogenation of carbonyl derivatives.

This manuscript describes the synthesis of a triazolyl-pyridine-based phosphine, -((diphenylphosphaneyl)methyl)--methyl-6-(1-phenyl-1-1,2,3-triazol-4-yl)pyridin-2-amine, [2,6-{(PPh)CHN(Me)(CHN)(CHNCH)}] (1) (here onwards referred to as PNN) and its cationic and neutral Mn complexes and catalytic applications. The reaction of 1 with Mn(CO)Br afforded a cationic complex [Mn(CO)(PNN)]Br (2), which is highly stable in solid state, but in solution it gradually loses one of the CO groups to form a neutral complex [Mn(CO)(PNN)Br] (3). Complex 2 on treatment with AgBF also yielded a cationic complex [Mn(CO)(PNN)]BF (4). These complexes efficiently promoted the synthesis of quinoline derivatives acceptor-less dehydrogenative coupling of 2-aminobenzyl alcohol and ketones, with complex 3 showing the highest activity with a very low catalyst loading (0.03 mol%) at 110 °C. Complex 3 (0.5 mol%) also showed excellent catalytic activity in the transfer hydrogenation of ketones and aldehydes to form respective secondary and primary alcohols.