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One-dimensional (1D) Cd(II) coordination polymers [Cd(-SPhOMe)] ( = , , and ; HSPhOMe = methoxybenzenethiol) containing inorganic 1D (-Cd-S-) chains were synthesized. Among these, the KGF-31 polymer bearing -SPhOMe featured a three-strand chain structure assembled interchain S⋯S interactions and exhibited high photoconductivity and longevity.
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http://dx.doi.org/10.1039/d3cc05689a | DOI Listing |