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Article Abstract
The reaction of the six-vertex amido-substituted silicon cluster Si{N(SiMe)Ph} 1 with two equiv. of KC results in the abstraction of K{N(SiMe)Ph} and leads to the contact ion pair 2 including an anionic silicon cluster with two unsubstituted pyramidal vertices. Facile functionalization of 2 was achieved with MeI, SiCl and SiBr and results in neutral two-fold functionalized silicon clusters.
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| http://dx.doi.org/10.1039/d2dt03952d | DOI Listing |
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