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In many fields, such as environmental monitoring, food safety, and medical diagnostics, the identification of organic compounds is essential. It is crucial to create exceptionally sensitive and selective sensors for the detection of organic compounds in order to safeguard the environment and human health. Due to its outstanding electrical, mechanical, and chemical characteristics, the two-dimensional carbon substance graphene has recently attracted much attention for use in sensing applications. The purpose of this research is to create an organic material sensor made from graphene for the detection of organic substances like phenol, ethanol, methanol, chloroform, etc. Due to its high surface-to-volume ratio and potent interactions with organic molecules, graphene improves the sensor's performance while the metasurface structure enables the design of highly sensitive and selective sensing elements. The suggested sensor is highly sensitive and accurate at detecting a broad spectrum of organic molecules, making it appropriate for a number of applications. The creation of this sensor has the potential to have a substantial impact on the field of organic sensing and increase the safety of food, medicine, and the environment. The graphene metasurface organic material sensor (GMOMS) was categorized into three types denoted as GMOMS1, GMOMS2, and GMOMS3 based on the specific application of the graphene chemical potential (GCP). In GMOMS1, GCP was applied on both the CSRR and CS surfaces. In GMOMS2, GCP was applied to the CS surface and the surrounding outer region of the CSRR. In GMOMS3, GCP was applied to the CSRR and the surrounding outer region of the CSRR surface. The results show that all three designs exhibit high relative sensitivity, with the maximum values ranging from 227 GHz/RIU achieved by GMOMS1 to 4318 GHz/RIU achieved by GMOMS3. The FOM values achieved for all the designs range from 2.038 RIU achieved by GMOMS2 to 31.52 RIU achieved by GMOMS3, which is considered ideal in this paper.
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http://dx.doi.org/10.3390/bios13080759 | DOI Listing |
Inorg Chem
September 2025
Yunnan Key Laboratory of Crystalline Porous Organic Functional Materials, College of Chemical and Materials Engineering, Qujing Normal University, Qujing 655011, China.
Sequential assembly of donor-acceptor components at the molecular level within a MOF is an effective strategy to achieve efficient electron-hole separation for enhancing the activity of photocatalysts. Meanwhile, the highly efficient and selective functionalization of tetrahydroisoquinoline (THIQ) under mild conditions remains an urgent demand in both the scientific and industrial communities. This work reports a donor-acceptor MOF photocatalyst () constructed by the coordinated assembly of donor and acceptor components, in which a naphthalene unit serves as an electron donor and a perylenediimide unit as an electron acceptor.
View Article and Find Full Text PDFJ Agric Food Chem
September 2025
College of Materials and Chemistry & School of Plant Protection, Anhui Agricultural University, Hefei, 230036, P. R. China.
In recent years, the hydrazide skeleton, as a pivotal class of nitrogen-containing structures, has garnered considerable attention in medicinal chemistry and organic synthesis owing to its unique chemical versatility and broad-spectrum biological activities. In this study, a series of thiazole-containing benzoylhydrazine derivatives -, -, and - with structural divergence from conventional hydrazide-based molecular frameworks were designed, synthesized, and evaluated for their antifungal/antioomycete activities. The antifungal/antioomycete assay showed that some of the targeted compounds exhibited remarkable and broad-spectrum antifungal activities.
View Article and Find Full Text PDFJ Org Chem
September 2025
Department of Organic Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, P R China.
The electrochemical trifluoromethylation/1,5-HAT of -cyanamide alkenes with CFSONa has been achieved to construct trifluoromethylated cyclic amidines and -acryloylpyrrolidin-2-one derivatives. This transformation was performed with readily available starting materials under mild conditions and required neither oxidants nor transition metal catalysts, exhibiting high atom economy.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
School of Chemistry and Chemical Engineering, Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China.
Additive assisted strategies play a crucial role in optimizing the morphology and improving the performance of organic solar cells (OSCs), yet the molecular-level mechanisms remain unclear. Here, we employ molecular dynamics (AIMD) and density functional theory (DFT) to elucidate the influence of typical additives of 1,8-diiodooctane (DIO) and 3,5-dichlorobromobenzene (DCBB) on molecular packing, electronic structures, and charge transport. It can be observed that both additives can enhance the stacking properties of the donor and acceptor materials, yet they have different effects on the local electrostatic environment.
View Article and Find Full Text PDFBioprocess Biosyst Eng
September 2025
Department of Life Sciences, Chhatrapati Shahu Ji Maharaj University, Kanpur, 208024, India.
The development of innovative bioprocessing technologies has resulted from the growing global need for sustainable forms of energy and environmentally friendly waste treatment. In this review, we focus on the combined electro-fermentation and microbial fuel cells, as they form a hybrid system that simultaneously addresses wastewater treatment, bioenergy production, and bioplastics. Even though microbial fuel cells produce electricity out of the organic waste by the use of electroactive microorganisms, electro-fermentation improves the microbial pathways through the external electrochemical management.
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