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The massive exploration and random dumping of coals in various regions of China create serious environmental and health problems because of the presence of toxic trace elements (TTEs), which possibly transfer to environment and cause serious health issues. This study was conducted to probe the environmental consequences of coalmines on the aquifer water and their association with health risks and the environment. For this purpose, 100 s of water samples was collected from the typical coalmine regions of Hancheng, Huanglong, Binxian, Handan, Langao, and Fusui and analyzed for various parameters. In Handan mining areas, Se, Mn, Fe, TDS, SO, and total hardness were higher than the WHO standard, while in Hancheng, SO was > 95%, Ca 40-96%, and Mg was 0-40%, which caused permanent hardness. In the Fusui and Huanglong areas, the SO concentration was > 95%, Ca 60-100%, and Mg 20%, causing permanent hardness. In Binxian, HCO was 70-90%, Ca 60-80%, and Cl and SO were 20%, causing temporary hardness. In the Kashin-Beck disease (KBD) area, Se in the Middle Triassic was 0.3, Upper Triassic 0.23, and Quaternary 0.01, while fluoride (F) was 124.7, 141.6, and 159 in μg L. The Handan water is included in rock-evaporation dominance (a mixed controlling mechanism), Hancheng, Binxian, Huanglong, and Langao water was included in rock dominance, while the Fusui water was included in rock-precipitation dominance. The average daily intake ((ADI) mg kg d) of Ba, Cd, Co, Cr, Cu, Fe, Ti, Tl, Mo, Ni, Zn, Pb, Be, U, and Sr was comparably higher than No Observed Adverse Effect Level (NOAEL), which surely causes high health risk in selected regions. The elemental contaminants in the water were attributed to the geological environment, geochemical processes, ion exchanges, redox reactions, and dissolution of mineralized rock. For aquifer safety, coal mining, and other geological activities should be avoided to protect the water for future generations.
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http://dx.doi.org/10.1007/s10653-023-01716-3 | DOI Listing |
Mult Scler
September 2025
Neuroimaging Unit, Neuroimmunology Division, Department of Neurology, Vanderbilt University Medical Center, Nashville, TN, USA; Department of Neurology, VA Medical Center, TN Valley Healthcare System, Nashville, TN, USA.
Background: There is limited knowledge on the post-glymphatic structures such as the parasagittal dural (PSD) space and the arachnoid granulations (AGs) in multiple sclerosis (MS).
Objectives: To evaluate differences in volume and macromolecular content of PSD and AG between people with newly diagnosed MS (pwMS), clinically isolated syndrome (pwCIS), or radiologically isolated syndrome (pwRIS) and healthy controls (HCs) and their associations with clinical and radiological disease measures.
Methods: A total of 69 pwMS, pwCIS, pwRIS, and HCs underwent a 3.
iScience
September 2025
Instituto de Biología Molecular y Celular de Plantas, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, 46022 Valencia, Spain.
Arbuscular mycorrhizal fungi (AMF) play a crucial role in disease control by establishing symbiotic relationships with plant roots. AMF improve salinity tolerance in plants by regulating the Na/K ratio through selective ion transport and mediate osmotic regulation by inducing the accumulation of osmotic-compatible solutes such as glycine betaine and proline to enable plant cells to maintain water content and the metabolic balance. AMF can also activate antioxidant defense responses by stimulating enzymes that protect plant cells from harmful oxidation and pathological infections.
View Article and Find Full Text PDFBeilstein J Nanotechnol
August 2025
Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León. San Nicolás de los Garza, Nuevo León, 66455, México.
Nanoparticles in their pure colloidal form synthesized by laser-assisted processes such as laser ablation/fragmentation/irradiation/melting in liquids have attained much interest from the scientific community because of their specialties like facile synthesis, ultra-high purity, biocompatibility, colloidal stability in addition to other benefits like tunable size and morphology, crystalline phases, new compounds and alloys, and defect engineering. These nanocolloids are useful for fabricating different devices mainly with applications in optoelectronics, catalysis, sensors, photodetectors, surface-enhanced Raman spectroscopy (SERS) substrates, and solar cells. In this review article, we describe different methods of nanocolloidal synthesis using laser-assisted processes and corresponding thin film fabrication methods, particularly those utilized for device fabrication and characterization.
View Article and Find Full Text PDFBeilstein J Nanotechnol
August 2025
Faculty of Engineering and Technology, Saigon University, 273 An Duong Vuong Street, Cho Quan Ward, Ho Chi Minh City 700000, Vietnam.
This study employs a bibliometric analysis using CiteSpace to explore research trends on the impact of biochar on microplastics (MPs) in soil and water environments. In agricultural soils, MPs reduce crop yield, alter soil properties, and disrupt microbial diversity and nutrient cycling. Biochar, a stable and eco-friendly material, has demonstrated effectiveness in mitigating these effects by restoring soil chemistry, enhancing microbial diversity and improving crop productivity.
View Article and Find Full Text PDFRSC Adv
September 2025
Department of Chemistry, University of Guelph Guelph ON N1G 2W1 Canada
In the context of the importance of manganese β-diketonates as precursors for the preparation of manganese oxide thin films and nanostructured materials, we report synthetic protocols and pitfalls encountered in the preparation of a family of Mn(ii) complexes of two fluorinated β-diketonates, 1,1,1-trifluoroacetylacetonato- (tfac) and 1,1,1,5,5,5-hexafluoroacetylacetonato- (hfac). The synthetic conditions and crystal structures of six new complexes are reported, including a coordination polymer {K[Mn(tfac)]}, an unusual trinuclear complex Mn(tfac)(OH), and a series of mononuclear complexes with coordinated solvents tetrahydrofuran, 1,2-dimethoxyethane, water, and acetonitrile. The crystal structures of two known Mn(ii) complexes are also reported for completeness.
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