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Article Abstract
Aggregating gold(I) complexes in solution through short aurophilic contacts promotes new photoluminescent deactivation pathways (aggregation-induced emission, AIE). The time dependence of spontaneous AIE is seldom studied. We examine the behavior of complex [Au(-hypoxanthinate)(PTA)] () in an aqueous solution with the aid of variable-temperature NMR, time-resolved UV-Vis and photoluminescence spectroscopy, and PGSE NMR. The studies suggest that partial ligand scrambling in favor of the ionic [Au(PTA)][Au(-hypoxanthinate)] pair followed by anion oligomerization takes place. The results are rationalized with the aid of computational calculations at the TD-DFT level of theory and IRI analysis of the electron density.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420115 | PMC |
| http://dx.doi.org/10.3390/molecules28155680 | DOI Listing |
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