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Graphene quantum dots (GQDs) are carbon-based zero-dimensional materials that have received considerable scientific interest due to their exceptional optical, electrical, and optoelectrical properties. Their unique electronic band structures, influenced by quantum confinement and edge effects, differentiate the physical and optical characteristics of GQDs from other carbon nanostructures. Additionally, GQDs can be synthesized using various top-down and bottom-up approaches, distinguishing them from other carbon nanomaterials. This review discusses recent advancements in GQD research, focusing on their synthesis and functionalization for potential applications. Particularly, various methods for synthesizing functionalized GQDs using different doping routes are comprehensively reviewed. Based on previous reports, current challenges and future directions for GQDs research are discussed in detail herein.
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http://dx.doi.org/10.1002/smll.202304497 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Center for Graphene Research and Innovation, University of Mississippi, University, Mississippi 38677, United States.
To assess the efficacy of a mixed-dimensional van der Waals (vdW) heterostructure in modulating the optoelectronic responses of nanodevices, the charge transport properties of the transition-metal dichalcogenide (TMD)-based heterostructure comprising zero-dimensional (0D) WS quantum dots (QDs) and two-dimensional (2D) MoS flakes are critically analyzed. Herein, a facile strategy was materialized in developing an atomically thin phototransistor assembled from mechanically exfoliated MoS and WS QDs synthesized using a one-pot hydrothermal route. The amalgamated photodetectors exhibited a high responsivity of ∼8000 A/W at an incident power of 0.
View Article and Find Full Text PDFSmall
September 2025
Department of Semiconductor Physics and Institute of Quantum Convergence Technology, Kangwon National University, Chuncheon, 24341, South Korea.
2D van der Waals ferromagnets hold immense promise for spintronic applications due to their controllability and versatility. Despite their significance, the realization and in-depth characterization of ferromagnetic materials in atomically thin single layers, close to the true 2D limit, has been scarce. Here, a successful synthesis of monolayer (ML) 1T-CrTe is reported on a bilayer graphene (BLG) substrate via molecular beam epitaxy.
View Article and Find Full Text PDFACS Nano
September 2025
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.
Visible-light activation is highly desirable for gas sensors due to its energy-efficient operation and broad accessibility. Photocatalysis offers a promising strategy for visible-light activation; however, a limited understanding of the band engineering-mediated activation process restricts the rational design of photocatalysts for gas sensors. In this work, we systematically investigate the impact of band tuning in photocatalysts on the nitrogen dioxide (NO) sensing performance of InO-based sensors, employing graphene quantum dots (GQDs) as photosensitizers.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Department of Chemistry, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Well-defined heterostructures exhibit emergent properties distinct from their single-phase constituents, enabling advances across diverse technologies. Typically classified as self-assembly and epitaxy, heterointerface formation is generally assumed to proceed unidirectionally and irreversibly at bulk scales. Here we use in situ electron microscopy at 298 K to visualize the heterostructure formation from nanoscale mixtures of intrinsically immiscible salts at ambient conditions, NaCl and NaI.
View Article and Find Full Text PDFACS Nano
September 2025
Hefei National Research Center for Physical Sciences at the Microscale, CAS Key Laboratory of Strongly-Coupled Quantum Matter Physics, Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026, China.
As a versatile platform for exploring exotic quantum phases, moiré superlattices, ranging from twisted graphene to twisted transition metal dichalcogenides, have been intensively studied. In this work, based on exact diagonalization and Hartree-Fock mean-field calculations, the interaction-driven topological phases are investigated in hole-doped twisted bilayer MoS at the high filling factor = 3. Besides the nematic insulator and quantum anomalous Hall phases, the topological Wigner molecule crystal (TWMC) phase is found in the phase diagram.
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