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The present work revisits and improves the Shannon entropy approach when applied to the estimation of an instability timescale for chaotic diffusion in multidimensional Hamiltonian systems. This formulation has already been proved efficient in deriving the diffusion timescale in 4D symplectic maps and planetary systems, when the diffusion proceeds along the chaotic layers of the resonance's web. Herein the technique is used to estimate the diffusion rate in the Arnold model, i.e., of the motion along the homoclinic tangle of the so-called guiding resonance for several values of the perturbation parameter such that the overlap of resonances is almost negligible. Thus differently from the previous studies, the focus is fixed on deriving a local timescale related to the speed of an Arnold diffusion-like process. The comparison of the current estimates with determinations of the diffusion time obtained by straightforward numerical integration of the equations of motion reveals a quite good agreement.
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http://dx.doi.org/10.1103/PhysRevE.107.064101 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Leibniz-Institut für Katalyse e.V. (LIKAT), Albert-Einstein-Str. 29a, Rostock 18059, Germany.
Metal-organic frameworks (MOFs) are transformative platforms for heterogeneous catalysis, but distinguishing atomically dispersed metal sites from subnanometric clusters remains a major challenge. This often demands the integration of multiple characterization techniques, many of which either lack the resolving power to distinguish active sites from their surrounding environments (e.g.
View Article and Find Full Text PDFSelective and rapid detection of ammonia (NH) gas over a wide concentration range is essential for applications such as early diagnosis of renal diseases and environmental safety. NH in exhaled breath serves as a biomarker of kidney function, and its precise detection is vital for early renal disease diagnosis. This work reports a SnS/PANI heterojunction nanocomposite (SPA) sensor synthesized a hydrothermal route followed by oxidative polymerization.
View Article and Find Full Text PDFLab Chip
September 2025
Department of Engineering Design, Indian Institute of Technology Madras, India.
Microfluidic devices offer more accurate fluid flow control and lower reagent use for uniform nanoparticle synthesis than batch synthesis. Here, we propose a microfluidic device that synthesizes uniform iron oxide nanoparticles (IONPs) for highly efficient intracellular delivery. The 3D-printed device was fabricated, comprising two inlets in the T-shaped channel with an inner diameter of 2 mm, followed by a helical mixing channel with a single outlet.
View Article and Find Full Text PDFJ Feline Med Surg
September 2025
Department for Small Animals, Veterinary Faculty, Leipzig University, Leipzig, Germany.
ObjectivesThe objective of this study was to evaluate the occurrence of voltage-gated potassium channel (VGKC) antibodies and the pattern of MRI changes in cats with complex partial seizures with orofacial involvement (CPSOFI), as well as to investigate whether there are factors influencing survival that could be used as prognostic markers in those cats.MethodsCats with CPSOFI were identified retrospectively. The following data were retrieved from the hospital database: signalment, age at first seizure and presentation, the presence of antibodies against VGKC (leucine-rich glioma inactivating factor 1 (LGI1), contactin-associated protein 2 (CASPR2)) and cerebrospinal fluid (CSF) analysis findings.
View Article and Find Full Text PDFJ Hazard Mater
September 2025
State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), Harbin Institute of Technology, Harbin 150090, China; School of Environment, Harbin Institute of Technology, Harbin 150090, China. Electronic address:
The widespread discharge of emerging micropollutants (EMs) into sewer systems has raised serious environmental concerns throughout the world. However, the transformation mechanisms underlying the accumulation of EMs in sewer sediments remain largely unexplored. This study investigated the transformation fate and mechanisms of chloroxylenol (PCMX) in sewer sediments.
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