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Article Abstract
The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2'-biphenyl)(CxP)(N)] are described, where CxP is a -spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9933454 | PMC |
| http://dx.doi.org/10.1039/d2cc06837k | DOI Listing |
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Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.
Chem Commun (Camb)
February 2023
Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK.
The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2'-biphenyl)(CxP)(N)] are described, where CxP is a -spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.
View Article and Find Full Text PDFRhodocenium Functionalization Enabled by Half-Sandwich Capping, Zincke Reaction, Diazoniation and Sandmeyer Chemistry.
Eur J Inorg Chem
August 2021
Institute of General, Inorganic and Theoretical Chemistry University of Innsbruck Center for Chemistry and Biomedicine Innrain 80-82 6020 Innsbruck Austria.
In continuation of our exploration of metallocenium chemistry we report here on innovative ways toward monofunctionalized rhodocenium salts applying half-sandwich capping reactions of cyclopentadienyl rhodium(III) halide synthons with cyclopentadienyl ylides containing pyridine, phosphine or dinitrogen leaving groups, followed by Zincke and Sandmeyer reactions. Thereby amino, diazonio, bromo, azido and iodo rhodocenium salts containing valuable functional groups are accessible for the first time. Target compounds were characterized by spectroscopic (H/C/Rh-NMR, IR, HR-MS), structural (single crystal XRD) and electrochemical (CV) methods and their properties were compared to those of isoelectronic cobaltocenium compounds.
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