Seed-Derived Hierarchically Porous Carbon Materials for High-Performance Supercapacitor Applications.

The electrical double-layer supercapacitance performance of the nanoporous carbons prepared from the (Amala) seed by chemical activation using the potassium hydroxide (KOH) activator is reported. KOH activation was carried out at different temperatures (700-1000 °C) under nitrogen gas atmosphere, and in a three-electrode cell set-up the electrochemical measurements were performed in an aqueous 1 M sulfuric acid (HSO) solution. Because of the hierarchical pore structures with well-defined micro- and mesopores, seed-derived carbon materials exhibit high specific surface areas in the range of 1360 to 1946 m g, and the total pore volumes range from 0.664 to 1.328 cm g. The sample with the best surface area performed admirably as the supercapacitor electrode-material, achieving a high specific capacitance of 272 F g at 1 A g. Furthermore, it sustained 60% capacitance at a high current density of 50 A g, followed by a remarkably long cycle-life of 98% after 10,000 subsequent charging/discharging cycles, demonstrating the electrode's excellent rate-capability. These results show that the seed would have significant possibilities as a sustainable carbon-source for the preparing high-surface-area activated-carbons desired in high-energy-storage supercapacitors.