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Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar. | LitMetric
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Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar.

Charles J McMonagle , Gemma F Turner , Isabelle Jones , David R Allan , Mark R Warren , Konstantin V Kamenev , Simon Parsons , Paul A Wright , Stephen A Moggach

Chem Commun (Camb)

School of Molecular Sciences, The University of Western Australia, 35 Stirling Highway, Crawley, Perth, 6009, Western Australia, Australia.

Published: October 2022

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Article Abstract

Guest-mediated pore-shape modification of the metal-organic framework, ScBDC upon adsorption of -pentane and isopentane is examined from 50-1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.

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http://dx.doi.org/10.1039/d2cc04649kDOI Listing

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