Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Carbones are divalent carbon(0) species that contain two lone pairs of electrons. Herein, we have prepared the first known stable and isolable free bis-(carbone) pincer framework with a well-defined solid-state structure. This bis-(carbone) ligand is an effective scaffold for forming monometallic (Ni and Pd) and trinuclear heterometallic complexes with Au-Pd-Au, Au-Ni-Au, and Cu-Ni-Cu configurations. Sophisticated quantum-theoretical analyses found that the metal-metal interactions are too weak to play a significant role in upholding these multi-metallic configurations; rather, the four lone pairs of electrons within the bis-(carbone) framework are the main contributors to the stability of the complexes.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.202201884 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Binuclear Macrocyclic Silver(I) Complex of a Bis(carbone) Pincer Ligand: Synthesis and Application as a Carbone-Transfer Agent.
Inorg Chem
August 2023
Institute of Chemistry, Academia Sinica, Taipei 11529, Taiwan.
A facile synthesis of a binuclear Ag complex of a bis(carbone) ligand and its application as a carbone-transfer agent for the generation of other transition-metal complexes of Au (), Ni (), and Pd () is presented. Complex was synthesized through multiple synthetic routes under mild reaction conditions using the tetracationic [H][OTf·Cl] precursor salt, the dicationic [H][OTf] ylide salt, and the free ligand . The first two synthesis routes require no prior isolation of the air-, moisture-, and temperature-sensitive free ligand , thus affording complex with high yield and purity.
View Article and Find Full Text PDFA Bis-(carbone) Pincer Ligand and Its Coordinative Behavior toward Multi-Metallic Configurations.
Angew Chem Int Ed Engl
June 2022
Institute of Chemistry, Academia Sinica, Taipei, Taiwan, ROC.
Carbones are divalent carbon(0) species that contain two lone pairs of electrons. Herein, we have prepared the first known stable and isolable free bis-(carbone) pincer framework with a well-defined solid-state structure. This bis-(carbone) ligand is an effective scaffold for forming monometallic (Ni and Pd) and trinuclear heterometallic complexes with Au-Pd-Au, Au-Ni-Au, and Cu-Ni-Cu configurations.
View Article and Find Full Text PDF