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Article Abstract
A berkelium(III) mellitate, Bk[C(CO)](HO)·2HO, was synthesized and rapidly crystallized by reacting mellitic acid, C(COH), and BkBr·HO in an aqueous medium. Single crystal X-ray diffraction shows that the compound crystallizes as a three-dimensional framework isostructural with Pu(III), Am(III), and Cm(III) mellitates. UV-vis-NIR spectroscopic studies as a function of pressure were performed using a diamond anvil cell and show that the 5f → 5f transitions of Bk display enhanced hypsochromic shifting when compared to other An(III) mellitates.
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