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Experimental data for green synthesis of Zn-abietate complex from natural resin. | LitMetric

Experimental data for green synthesis of Zn-abietate complex from natural resin.

Data Brief

Departament of Chemistry, Universidade Estadual do Centro-Oeste, UNICENTRO, Alameda Elio Antonio Dalla Vecchia, 838, Guarapuava, PR 85040-167, Brazil.

Published: February 2022


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Article Abstract

This data article is associated with the work "Ecofriendly synthesis of Zn-abietate complex derived from resin and its application as an antibacterial pigment against and ". The characterization data of the Zn-abietate complex obtained from resin and their reactional intermediary (Na-abietate) are reported. The Na-abietate was prepared with purified Pinus resin and sodium hydroxide (≥ 99%) in a stoichiometric ratio of 1:1. For the Zn-abietate synthesis was used ZnSO and Na-abietate solutions were at mild temperature and stirring without using organic solvents to ensuring the green character of the synthesis. Spectroscopic and structural characterization was consistent with an octahedral complex involving three carboxylate ligands per metal ion. X-ray photoelectron spectroscopy (XPS) analysis of the Na-abietate salt confirms the presence of carbonyl groups, carbon-oxygen atoms simple bonds (O-C/O=C), and carboxylate groups oxygen atoms (O-C=O). Analysis of the Zn LMM Auger, for the Zn-abietate complex, indicates the presence of zinc atoms with oxidation state Zn, this is supported by the distance between Zn 2p and 1p in the XPS spectrum. Together, these data will be useful for the structural representation of the samples.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8741433PMC
http://dx.doi.org/10.1016/j.dib.2021.107776DOI Listing

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