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Article Abstract
This paper reports the first example of C-H arylation of benzene under mild conditions, using H as an electron source {turnover numbers (TONs)=0.7-2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H is inactive during the radical transfer step, greatly reducing unwanted side reactions.
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| http://dx.doi.org/10.1002/chem.202102735 | DOI Listing |
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