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Water-saturated column experiments were conducted to study the effect of nonwoven geotextiles on bacteria transport and deposition through two sandy porous media with grain sizes 1.05 and 3.25 mm. The breakthrough curves (BTCs) of tracer for the all porous media exhibited an asymmetrical shape with a substantial tailing, indicating that non-equilibrium and dispersive flow patterns in these porous media. The mass recovery of the bacteria from the effluent (M) increased with grain size. The retention profiles (RPs) exhibited hyper-exponential behavior, especially in the finer sand. The presence of the geotextiles increased bacteria retention rate. For a given geotextile, greater retention was observed in the surrounding region close to the geotextile. Moreover, the retention of bacteria became more significant in the geotextile with a lower porosity. Results demonstrated that model simulations of bacteria transport and fate need to accurately account for both observed BTC and RP behaviors and also the geotextile placement can impact mechanisms of retention.
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http://dx.doi.org/10.1016/j.colsurfb.2021.112114 | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Department of Chemistry, University of Wisconsin-Madison, 1101 University Ave., Madison, Wisconsin 53706, United States.
Slippery liquid-infused porous surfaces (or "SLIPS") can prevent bacterial surface fouling, but they do not inherently possess the means to kill bacteria or reduce cell loads in surrounding media. Past reports show that the infused liquids in these materials can be leveraged to load and release antimicrobial agents, but these approaches are generally limited to the use of hydrophobic agents that are soluble in the infused oily phases. Here, we report the design of so-called "proto-SLIPS" that address this limitation and permit the release of highly water-soluble (or oil-insoluble) agents.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Instituto de Cerámica y Vidrio (ICV-CSIC), C/Kelsen 5, 28049 Madrid, Spain.
The oxygen reduction reaction (ORR) is critical to energy conversion technologies and requires efficient catalysts for superior performance. Herein, nitrogen-doped carbide-derived carbon (N-CDC) catalysts are prepared using novel engineered molecular architectures based on polymer-derived ceramic technology. The obtained catalyst materials show a surface N concentration of >5 wt % and a hierarchically porous structure, resulting in a specific surface area of over 2000 m g.
View Article and Find Full Text PDFSnS (tin disulfide) is a promising anode active material for lithium-ion batteries (LIBs) due to its high theoretical capacity and low material cost. Conventional synthesis methods, such as solvothermal, hydrothermal, and solid-state, require long synthesis times, the use of solvents and surfactants, and several separation steps. However, the preparation of coated SnS composites using liquid media is even more complex, requiring suitable precursors, compatible solvents, and potentially several steps.
View Article and Find Full Text PDFLangmuir
September 2025
Key Laboratory of Green Chemical Media and Reactions (Ministry of Education), Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, P. R. China.
Recent years have witnessed growing research interest in proton-conducting metal-organic frameworks (MOFs) owing to the characteristics of highly ordered pores, oriented packing of crystals, and particularly designable structures. However, how to construct a suitable microenvironment in MOF pores to form optimal proton transport pathways remains challenging. In this study, four MOFs with similar porous diameters but different microenvironments have been screened to study how porous environments influence proton conduction for the first time.
View Article and Find Full Text PDFVertical cutoff wall is widely used as one of the in-situ remediation technologies for contaminated sites. In this paper, considering the unsaturated characteristics of porous media, a three-dimensional pollutant transport model of inner aquifer-vertical cutoff wall-outer aquifer is established. The main conclusions are as follows.
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