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Article Abstract
Photoswitchable acylhydrazone-based synthetic anionophores are reported. Single-crystal X-ray structure and H NMR titration studies confirmed the chloride binding in solid and solution states. The ion transport activity of was greatly attenuated through a phototriggered to photoisomerization process, and the photoisomerized deactivated state showed high kinetic stability due to an intramolecular hydrogen bond. Switchable "OFF-ON" transport activity was achieved by the application of light and acid-catalyzed reactivation process.
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| http://dx.doi.org/10.1021/acs.orglett.1c02249 | DOI Listing |
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