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Non-invasive comparative analysis of the spectral composition of energy absorbed by crop species at leaf and plant levels was carried out using the absorption coefficient retrieved from leaf and plant reflectance as an informative metric. In leaves of three species with contrasting leaf structures and photosynthetic pathways (maize, soybean, and rice), the blue, green, and red fractions of leaf absorption coefficients were 48, 20, and 32%, respectively. The fraction of green light in the total budget of light absorbed at the plant level was higher than at the leaf level approaching the size of the red fraction (24% green vs. 25.5% red) and surpassing it inside the canopy. The plant absorption coefficient in the far-red region (700-750 nm) was significant reaching 7-10% of the absorption coefficient in green or red regions. The spectral composition of the absorbed light in the three species was virtually the same. Fractions of light in absorbed PAR remained almost invariant during growing season over a wide range of plant chlorophyll content. Fractions of absorption coefficient in the green, red, and far-red were in accord with published results of quantum yield for CO fixation on an absorbed light basis. The role of green and far-red light in photosynthesis was demonstrated in simple experiments in natural conditions. The results show the potential for using leaf and plant absorption coefficients retrieved from reflectance to quantify photosynthesis in each spectral range.
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http://dx.doi.org/10.1007/s11120-021-00863-x | DOI Listing |
ACS Appl Mater Interfaces
September 2025
Department of Organic and Nano Engineering, and Human-Tech Convergence Program, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea.
Photomultiplication-type organic photodetectors (PM-type OPDs) have recently attracted attention. However, the development of polymer donors specifically tailored for this architecture has rarely been reported. In this study, we synthesized benzobisoxazole-based polymer donors incorporating alkylated π-spacers that simultaneously enhance photocurrent density () and suppress dark current density (), leading to high responsivity () and specific detectivity (*).
View Article and Find Full Text PDFJ Mater Chem B
September 2025
Dipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum - Università di Bologna, Via Piero Gobetti, 85, Bologna 40129, Italy.
Donor-acceptor-donor (D-A-D) thiophene-based compounds, characterized by thiophene as a donor unit and benzothiadiazole (Bz) as an acceptor, represent an emerging class of theranostic agents for imaging and photodynamic therapy. Here, we expand this class of molecules by strategically varying the position of the electron-accepting unit within the oligothiophene (OT) backbone structure, realizing a series of different push-pull architectures (A-D, D-A-D, and D-A). This rational design allows for precise modulation of key photophysical parameters, including absorption and emission spectra, molar absorption coefficient, charge separation, and frontier molecular orbitals.
View Article and Find Full Text PDFEnviron Res
September 2025
School of Resources and Safety Engineering, University of Science and Technology Beijing, Beijing 100083, China; Key Laboratory of Safe and Green Mining of Metal Mines with Cemented Paste Backfill, National Mine Safety Administration, University of Science and Technology Beijing, Beijing 100083, Chi
Cemented paste backfill has made outstanding contributions to the large-scale consumption of phosphogypsum (PG), but poor water resistance significantly weakens the mechanical strength, promotes the leaching of total soluble phosphate (TP) and fluoride ions (F), and reduces its attractiveness in mine engineering. This research synthesized a curing agent (CA) using sodium methylsilicate, sodium silicate, and polyaluminum chloride (PAC). PG produced from Deyang Haohua Qingping Phosphate Mine Co.
View Article and Find Full Text PDFJ Phys Condens Matter
September 2025
Department of Physics, Jishou University, Renmin South Road, Jishou, Hunan, 416000, CHINA.
Based on the first-principles calculations, we theoretically investigate the electronic structure, interfacial and optical properties of the tellurene/ZnSe (namely α- and γ-Te/ZnSe) van der Waals heterostructures (vdWHs). In the most stable stacking pattern, the α-Te/ZnSe vdWH exhibits an indirect band gap of 0.41 eV and forms a type-I band alignment, while the γ-Te/ZnSe vdWH possesses a p-type Schottky contact with a favorable Schottky barrier height of 0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
National Laboratory of Solid State Microstructures, School of Physics, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
For optoelectronic devices based on lead-halide perovskites and other semiconductors, a comprehensive understanding of the electric field influences on the carrier transport characteristics is critical to the optimization of their practical performances. To fulfill this challenging goal, here we have employed photoluminescence spatial image and transient absorption microscopy measurements on an individual CsPbBr microplate biased at external voltages in an Au/CsPbBr/Au device. At the subpicosecond time scale, some photogenerated excitons are dissociated into free electrons and holes that drift toward the electrodes to leave behind unfilled defect sites, which are capable of scattering the residual excitons to yield a reduced diffusion coefficient.
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