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Article Abstract
The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7584306 | PMC |
| http://dx.doi.org/10.1016/j.tet.2019.04.028 | DOI Listing |
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Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes.
Tetrahedron
June 2019
Indiana University, Department of Chemistry, 800 E. Kirkwood Ave. Bloomington, IN 47405.
The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions.
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