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Article Abstract
In this report, we introduced poly(-vinylpyridine) (PVP, = 2, 4) as an electron-donating stabilizer for small (<2 nm) Au clusters and elucidated how coordinating pyridines affect the physical, optical, chemical, and catalytic properties of Au clusters. Spectroscopic measurements and theoretical calculation suggested the high electron-donating ability of PVP. PVP-stabilized Au clusters improved robustness in aerobic oxidation of alcohols compared to poly(-vinyl-2-pyrrolidone)-stabilized ones, while retaining catalytic activities.
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