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Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining HO Molecules. | LitMetric
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Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining HO Molecules.

Elí Sánchez-González , J Gabriel Flores , Julio C Flores-Reyes , Ivette Morales-Salazar , Roberto E Blanco-Carapia , Mónica A Rincón-Guevara , Alejandro Islas-Jácome , Eduardo González-Zamora , Julia Aguilar-Pliego , Ilich A Ibarra

Materials (Basel)

Laboratorio de Fisicoquímica y Reactividad de Superficies, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior S/N, Ciudad Universitaria, Coyoacán, C.P. 04510 Ciudad de México, Mexico.

Published: April 2020

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Article Abstract

The structure transformation of Mg-CUK-1 due to the confinement of HO molecules was investigated. Powder X-ray diffraction (PXRD) patterns were collected at different HO loadings and the cell parameters of the HO-loaded Mg-CUK-1 material were determined by the Le Bail strategy refinements. A bottleneck effect was observed when one hydrogen-bonded HO molecule per unit cell (18% relative humidity (RH)) was confined within Mg-CUK-1, confirming the increase in the CO capture for Mg-CUK-1.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7215401PMC
http://dx.doi.org/10.3390/ma13081840DOI Listing

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