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Article Abstract
The reaction between dipyriamethyrin and copper(II) acetate [Cu(OAc)] afforded what is, to our knowledge, the first transition metal-dipyriamethyrin complex. Molecular and electronic characterization of this binuclear Cu(II) complex via EPR, UV-vis, and single crystal X-ray diffraction analysis revealed marked differences between the present constructs and previously reported binuclear copper(II) hexaphyrin species. UV-vis titration analyses provided evidence for a homotropic positive allosteric effect, wherein the binuclear species is formed without significant intermediacy of a monomeric complex.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7145289 | PMC |
| http://dx.doi.org/10.3390/molecules25061446 | DOI Listing |
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