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Direct conversion of uranium dioxide UO to uranium tetrafluoride UF using the fluorinated ionic liquid [Bmim][PF]. | LitMetric
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Direct conversion of uranium dioxide UO to uranium tetrafluoride UF using the fluorinated ionic liquid [Bmim][PF].

Florian Joly , Pardis Simon , Xavier Trivelli , Mehdi Arab , Bertrand Morel , Pier Lorenzo Solari , Jean-Francois Paul , Philippe Moisy , Christophe Volkringer

Dalton Trans

Unité de Catalyse et Chimie du Solide (UCCS), UMR CNRS 8181, Université de Lille, ENSC-Lille, Bat. C7, Avenue Mendeleïev, 59655 Villeneuve d'Ascq, France.

Published: January 2020

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Article Abstract

The industrial fluorination of UO2 to UF4 is based on a complex process involving the manipulation of a large amount of HF, a very toxic and corrosive gas. We present here a safer way to accomplish this reaction utilizing ionic liquid [Bmim][PF6] as a unique reaction medium and fluoride source.

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 Source
http://dx.doi.org/10.1039/c9dt04327fDOI Listing

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