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We present methyl-ammonium lead iodide perovskite solar cells coupled with one-dimensional photonic crystals (PCs) to achieve enhancement in light harvesting and photocurrent efficiencies. The introduction of PCs as a light reflection layer in the solar cells attributes to the increase in light harvesting efficiency and photocurrent density, which can be tuned by controlling the PC parameters such as the number of layers and layer thickness. Another important feature of the design is the introduction of a thin Au/Ag layer on top, which lets through more than 70% sunlight incident on it into the device, protects the hole transporting layer, and also helps in containing the light reflected from the PC layer into the device for further harvesting. The effects of layer thickness of the perovskite, hole transporting, and metallic contact layers on solar absorption enhancement and photocurrent density are also studied to achieve high power conversion efficiencies. We propose the optimum structural parameters of the considered solar cell structures, which provide the required guidance and also give further opportunities in the design of organo-metal halide perovskite solar cells coupled with PC structures.
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http://dx.doi.org/10.1364/AO.58.008046 | DOI Listing |
J Phys Chem Lett
September 2025
Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87106, United States.
Defects significantly influence charge transport in CHNHPbI (MAPbI) perovskite solar cells, particularly at interfaces. Using quantum dynamics simulation, we reveal a distinct interstitial iodine (I) defect behavior at different positions in the TiO/MAPbI system. In the perovskite bulk-like region, I exhibits high mobility and dissociates detrimental iodine trimers, facilitating small-to-large polaron transition and promoting shallow trap formation.
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September 2025
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing, 100875, China.
This study presents a novel carbazole derivative functionalized with hydroxy diphosphonic acid groups (HDPACz) as an efficient annealing-free hole transport layer (HTL) through strong bidentate anchoring to indium tin oxide (ITO). Compared to conventional mono-phosphonic acid counterparts, HDPACz demonstrates superior ITO surface coverage and interfacial dipole, effectively modulating the work function of ITO. Theoretical calculations reveal enhanced adsorption energy (-3.
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September 2025
Key Laboratory of Nanosystem and Hierarchical Fabrication of Chinese Academy of Sciences, National Center for Nanoscience and Technology, Beijing, 100190, China.
All-small-molecule organic solar cells (ASM-OSCs) with completely definite chemical structure are an ideal model to establish the relationship between molecular structure and device performance via aggregates. The end-capped acceptor unit is of great significance in the regulation of aggregates by essential molecular interactions. However, the successful end-capped acceptor units for small-molecule donors have been rather poorly studied and only focused on the alkyl substituted rhodamine, limiting further development for ASM-OSCs.
View Article and Find Full Text PDFBeilstein J Nanotechnol
August 2025
Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León. San Nicolás de los Garza, Nuevo León, 66455, México.
Nanoparticles in their pure colloidal form synthesized by laser-assisted processes such as laser ablation/fragmentation/irradiation/melting in liquids have attained much interest from the scientific community because of their specialties like facile synthesis, ultra-high purity, biocompatibility, colloidal stability in addition to other benefits like tunable size and morphology, crystalline phases, new compounds and alloys, and defect engineering. These nanocolloids are useful for fabricating different devices mainly with applications in optoelectronics, catalysis, sensors, photodetectors, surface-enhanced Raman spectroscopy (SERS) substrates, and solar cells. In this review article, we describe different methods of nanocolloidal synthesis using laser-assisted processes and corresponding thin film fabrication methods, particularly those utilized for device fabrication and characterization.
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September 2025
School of Engineering and Technology, National Textile University 37640 Faisalabad Pakistan
[This retracts the article DOI: 10.1039/D4RA01544D.].
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