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Revisiting the water sorption isotherm of MOF using electrical measurements. | LitMetric

Revisiting the water sorption isotherm of MOF using electrical measurements.

Chem Commun (Camb)

Institut Charles Gerhardt Montpellier, UMR 5253 CNRS, UM, ENSCM Université Montpellier, Place E. Bataillon, 34095 Montpellier cedex 5, France.

Published: October 2019


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Article Abstract

Water adsorption/desorption isotherms of Cr-soc-MOF-1 were monitored electrically, with the translation of proton conductivity measurements to physisorption isotherms in terms of S-shape and hysteresis features revealed by volumetry. Molecular modelling further established the relationship between the evolutive water-hydrogen bonded network and the "electrical" isotherm for this water-mediated proton conducting MOF.

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Source
http://dx.doi.org/10.1039/c9cc06012jDOI Listing

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