High-Resolution, Fast, and Shape-Conformable Hydrogen Sensor Platform: Polymer Nanofiber Yarn Coupled with Nanograined Pd@Pt.

We report a flexible hydrogen sensing platform based on a single-strand yarn consisting of high-density electrospun nanofibers, on which nanograined Pd or Pd@Pt is coated via yarn spinning followed by sputter deposition. In general, Pd undergoes a phase transition to PdH (α-PdH at [H] < 1% and β-PdH at [H] > 2%), in which H atoms act as electron scattering centers, thus increasing the resistance. In our system, the sensors exhibit switchable H sensing behaviors, that is, (i) Δ R/ R > 0 at [H] > 1% by the active electron scattering and (ii) Δ R/ R < 0 at [H] < 1% derived from nanograined Pd effects. Due to high mechanical stability stemming from nanogranular morphologies of Pd, which is essential for enduring a huge volume expansion upon exposure to high-concentration H, we could obtain a wide concentration range (4-0.0001%) H detection resolution. Moreover, an ultrathin Pt overlayer coated on Pd offers an accelerated H detection capability based on effective gas dissociation and activation properties. Furthermore, by virtue of the core (thread)-shell (nanofiber yarn) scaffold, long cycling reliability and flexibility were achieved. This facile and low-cost yarn fabrication method offers the development of single-strand thread-type wearable chemiresistors that possess a high surface area and open porosity, facilitating gas diffusion and reaction.