Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Nuclear magnetic resonance (NMR) and total neutron scattering techniques are established methods for the characterisation of liquid phases in confined pore spaces during chemical reactions. Herein, we describe the first combined total neutron scattering - NMR setup as a probe for the catalytic heterogeneous reduction of benzene-d6 with D2 in 3 wt% Pt/MCM-41.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c8cc04740e | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A multicenter retrospective analysis of recurrent/metastatic nasopharyngeal cancer from non-endemic areas: Results in the pre-immunotherapy era.
Eur J Cancer
September 2025
Medical Oncology and Hematology Unit, IRCCS Humanitas Research Hospital, Rozzano, Milan, Italy; Department of Biomedical Sciences, Humanitas University, Milan, Italy.
Aim Of The Study: The aim of the study is to describe clinical features, treatment approach and outcomes of recurrent/metastatic (R/M) NPC in non-endemic areas MATERIALS AND METHODS: This observational, retrospective and multicenter study was conducted within 36 referral hospital in non-endemic areas including Europe, Jordan, Kuwait, Turkey and United States of America. All NPC patients diagnosed between 2004 and 2016 and with a minimum 12 months of follow-up were included. Data entry started in January 2018 and closed in December 2023.
View Article and Find Full Text PDFPhysicochemical characterization of polyoxyethylene (POE)-based nonionic surfactants in single and mixed micellar environments for anticancer drug solubilization enhancement.
Phys Chem Chem Phys
September 2025
Department of Chemistry, Veer Narmad South Gujarat University (VNSGU), Udhna - Magdalla Road, Surat-395007, Gujarat, India.
This work reports the nanoscale micellar formation in single and mixed surfactant systems by combining an amphiphilic graft copolymer, Soluplus® (primary surfactant), blended with other polyoxyethylene (POE)-based nonionic surfactants such as Kolliphor® HS15, Kolliphor® EL, Tween-80, TPGS®, and Pluronics® P123 in an aqueous solution environment. The solution behaviour of these surfactants as a single system were analyzed in a wide range of surfactant concentrations and temperatures. Rheological measurements revealed distinct solution behaviour in the case of Soluplus®, ranging from low-viscosity () and fluid-like behavior at ≤20% w/v to a highly viscous state at ≥90% w/v, where the loss modulus ('') exceeded the storage modulus (').
View Article and Find Full Text PDFLithium solvation and anion-dominated domain structure in water-in-salt electrolytes.
EES Batter
August 2025
Department of Chemistry, School of Chemistry, Food and Pharmacy, University of Reading Reading RG6 6AD UK
Water-in-Salt (WiS) electrolytes are an emerging class of high concentration aqueous electrolytes with large electrochemical stability windows, making them attractive as green alternatives in next-generation electrochemical energy storage devices. Recent work has highlighted the existence of water-rich and anion-rich domains in WiS electrolytes, but the extent, morphology and importance of these domains are still disputed. Here, we present neutron total scattering measurements of the archetypal WiS, lithium bis(trifluoromethanesulfonyl)imide, and use empirical potential structure refinement to match the structure of a simulated system to the experimental data for two technologically relevant concentrations, revealing ion solvation, geometric isomerism and long-range structures in unprecedented detail.
View Article and Find Full Text PDFCovalency and Lone Pair-Driven Distortions in Sulfur-Doped Tin Niobate.
Inorg Chem
August 2025
Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019, United States.
Heteroanionic materials can provide a powerful platform for tuning the local structure and electronic properties through targeted chemical substitution. Among them, heteroanionic pyrochlores offer exceptional flexibility due to their robust framework and capacity to host both cation and anion disorders. In this study, we investigate the structure-property relationship in sulfur-doped tin niobate SnNbOS, a lone pair-active pyrochlore where substitution of sulfur into the O' site systematically modulates both the electronic structure and local coordination environments.
View Article and Find Full Text PDFRole of the TGF-β/SMAD pathway in tumor radioresistance to boron neutron capture therapy (BNCT) in a human cell line of colon adenocarcinoma.
Appl Radiat Isot
August 2025
Centro Oncológico de Medicina Nuclear. Instituto de Oncología "Ángel H. Roffo" (Universidad de Buenos Aires-Comisión Nacional de Energía Atómica), Av. San Martín 5481 (1417), CABA, Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290, (C1425FQB),
BNCT is a radiotherapeutic modality of high LET energy for different solid tumors as colorectal carcinoma (CRC). Although clinical outcomes show advantages of BNCT, tumor recurrence remains a common challenge. Previously we have described the double strand DNA damage response (DDR) produced by BNCT.
View Article and Find Full Text PDF