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Catalysis of photooxidation reactions through transformation between Cu and Cu in TiO-Cu-MOF composites. | LitMetric
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Catalysis of photooxidation reactions through transformation between Cu and Cu in TiO-Cu-MOF composites.

Chunjun Chen , Tianbin Wu , Dexin Yang , Pei Zhang , Huizhen Liu , Youdi Yang , Guanying Yang , Buxing Han

Chem Commun (Camb)

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Published: June 2018

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Article Abstract

Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing the photocatalytic performance.

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http://dx.doi.org/10.1039/c8cc03505aDOI Listing

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