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Carbohydrate binding through first- and second-sphere coordination within aromatic oligoamide metallofoldamers. | LitMetric

Carbohydrate binding through first- and second-sphere coordination within aromatic oligoamide metallofoldamers.

Chem Commun (Camb)

Université de Bordeaux, CNRS, Bordeaux Institut National Polytechnique, CBMN (UMR 5248), IECB, 2 rue Robert Escarpit, F-33600 Pessac, France.

Published: May 2018


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Article Abstract

Aromatic oligoamide capsules that fold upon metal binding recognize carbohydrate guests in solution as evidenced by CD and NMR titrations. Crystallographic data reveal that, besides their structural role, metal ions also contribute to guest recognition through either first- or second-sphere coordination.

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http://dx.doi.org/10.1039/c8cc02360cDOI Listing

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