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Article Abstract

The reactions of the tetrahedral diphosphorus [CpMo(CO)(η-P)] (; Cp = CH) complex with Ag[Al{OC(CF)}] (AgTEF) () and Ag[FAl{OC(CF)(CF)}] (AgFAl) () were studied. The first reaction led to the formation of the [Ag(η-)(η:η-)][TEF] () dimer and the [Ag(η:η-)] [TEF] () coordination polymer, whereas the second reaction afforded the [Ag(η:η-)(η-CHCl)(η-CH)][FAl] () or the [Ag(η-)(η:η-)][FAl] () dimer and the [Ag(η:η-)] [FAl] () coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5586200PMC
http://dx.doi.org/10.1002/ejic.201700646DOI Listing

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