Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Several new mono- and difluoromethylation reactions of cinnamic acids using an Eosin Y catalytic system are reported. An efficient alkene fluoromethylation of α,β-unsaturated carboxylic acids was accomplished under ambient temperature and metal-free conditions, with a wide range of functional group tolerance. A mechanism that involves a radical process is proposed for this reaction.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.orglett.7b02129 | DOI Listing |
Publication Analysis
Top Keywords
mono- difluoromethylation
8
cinnamic acids
8
metal-free conditions
8
visible-light-enabled decarboxylative
4
decarboxylative mono-
4
difluoromethylation cinnamic
4
acids metal-free
4
conditions mono-
4
difluoromethylation reactions
4
reactions cinnamic
4