98%
921
2 minutes
20
An inorganic thermochromic material based on Cr-doped Al₂O₃ is synthesized using a solid-state method. The crystal structure, chemical composition, and morphology of the synthesized material are analyzed using X-ray diffraction, scanning electron microscopy coupled with an energy-dispersive X-ray spectrometer, and Fourier transform infrared (FT-IR) spectroscopy. The color performances of the synthesized material are analyzed using a UV-VIS spectrometer. Finally, the thermochromism exhibited by the powdered samples at high temperatures is investigated. The material exhibits exceptional thermochromic property, transitioning from pink to gray or green in a temperature range of 25-600 °C. The change in color is reversible and is dependent on the surrounding temperature and chromium concentration; however, it is independent of the exposure time. This novel property of Cr-doped Al₂O₃ can be potentially employed in reversible thermochromic sensors that could be used not only for warning users of damage due to overheating when the environmental temperature exceeds certain limits, but also for detecting and monitoring the temperature of various devices, such as aeronautical engine components, hotplates, and furnaces.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5459022 | PMC |
http://dx.doi.org/10.3390/ma10050476 | DOI Listing |
Inorg Chem
September 2025
Laboratory of Microscale Magnetic Resonance and Department of Physics, School of Physical Sciences, University of Science and Technology of China, Hefei 230026, China.
Anomalous NIR emission has been reported in Cr-doped SrPO, despite the Cr ions occupying nonstandard nine-coordinated Sr sites. Through first-principles calculations, we demonstrate that these environments induce structural distortions and nonradiative relaxation channels, effectively quenching luminescence. Photoluminescence data and energetic analysis instead attribute the observed emission (∼840 nm) to a coexisting phase, Sr(PO), where Cr substitutes for six-coordinated Sr, which is successfully verified in experiment.
View Article and Find Full Text PDFCommun Chem
August 2025
CEA, DES, IRESNE, DEC, Cadarache, F-13108, Saint-Paul-Lez-Durance, France.
Doping UO with Cr modifies the material's microstructure, enhancing its properties and making Cr-doped UO a promising candidate as accident-tolerant nuclear fuel (ATF). Numerous studies have examined the oxidation state and localization of Cr in UO but often yield inconsistent results, identifying either Cr or Cr as the most stable oxidation state. In the present study, DFT+U is employed to model the incorporation of Cr in the UO matrix, providing insights into the oxidation state of Cr in UO, in relation to the local atomic configurations.
View Article and Find Full Text PDFACS Omega
August 2025
Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia.
The adsorption of pentanal (PL), a volatile organic compound (VOC), is investigated on M (M = Mn, Cr) atom-modified arsenene systems using dispersion-corrected density functional theory (DFT+D3) calculations. Mn/Cr doping and/or Mn/Cr decoration strongly influences the electronic properties of arsenene and transform it into a narrow band gap semiconductor or half-metal with significant induced magnetism. The PL molecule is physically adsorbed on arsenene owing to the strong Coulomb repulsion of arsenic (As) atoms toward the molecule.
View Article and Find Full Text PDFThe transition metal Cr-doped ZnSe semiconductor is a kind of material that can realize laser output in the mid-infrared band and has broad application prospects in the fields of air monitoring, surgery, optical communication, industrial production, and national defense. In this work, the electronic structure, optical properties, and stability of ZnSe and ZnSe:Cr with vacancy defects introduced at Zn and Se sites were investigated. The vacancy affects the internal structure of the ZnSe crystal, where the Se vacancy increases the bandgap, but the Ze vacancy changes the semiconductor properties of ZnSe.
View Article and Find Full Text PDFRSC Adv
July 2025
Faculty of Materials Science and Engineering, Phenikaa School of Engineering, Phenikaa University Yen Nghia, Ha-Dong District Hanoi 12116 Vietnam.
Cr-activated phosphors, with their 3d electronic configuration, efficiently absorb blue/violet light and emit deep to far-red wavelengths, perfectly matching the optimal absorption bands for plant growth. In this work, we report the synthesis of YAlO-YAlO:1.3%Cr (YAG-YAP:Cr) phosphors exhibiting a broad emission spanning deep to far-red light, closely aligned with the far-red phytochrome (P) absorption spectrum in plants.
View Article and Find Full Text PDF