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Article Abstract
Oxygen atom transfer (OAT) reaction between an FeO complex and a Mn complex resulted in the eventual formation of their corresponding Fe and MnO complexes. The reaction proceeded via an initial fast OAT reaction between the FeO and Mn complexes, yielding a half equivalent of a MnO complex and a μ-oxo bridged Fe dimer. The dimer regenerated the FeO species via equilibrium, which then reacted with the remaining Mn complex to produce another half equivalent of the MnO complex.
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