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Flexoelectricity, the linear coupling of strain gradient and electric polarization, is inherently a size-dependent phenomenon. The energy storage function for a flexoelectric material depends not only on polarization and strain, but also strain-gradient. Thus, conventional finite-element methods formulated solely on displacement are inadequate to treat flexoelectric solids since gradients raise the order of the governing differential equations. Here, we introduce a computational framework based on a mixed formulation developed previously by one of the present authors and a colleague. This formulation uses displacement and displacement-gradient as separate variables which are constrained in a 'weighted integral sense' to enforce their known relation. We derive a variational formulation for boundary-value problems for piezo- and/or flexoelectric solids. We validate this computational framework against available exact solutions. Our new computational method is applied to more complex problems, including a plate with an elliptical hole, stationary cracks, as well as tension and shear of solids with a repeating unit cell. Our results address several issues of theoretical interest, generate predictions of experimental merit and reveal interesting flexoelectric phenomena with potential for application.
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http://dx.doi.org/10.1098/rspa.2015.0879 | DOI Listing |
Sci Adv
July 2025
National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
Domain engineering is essential in ferroelectric materials for controlling polar properties and attracts considerable attention because of its induced exotic phenomena and underlying rich physics. In recently discovered fluid ferroelectrics, dubbed ferroelectric nematics, the flexoelectric effect, which couples the gradient of the orientational field and the magnitude of polarizations, favors a splay polar field and can dominate over controlling polarization configurations. However, rationally designing and fabricating polarization fields with combinations of bend and twist, as well as the splay, remain a challenge.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2025
Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology,
Efficient conversion of solar energy into chemical fuels is pivotal for establishing sustainable energy systems, yet persistent challenges in carrier dynamics and reaction selectivity hinder practical implementation. This review systematically examines the emerging paradigm of "electricity" assisted solar-to-fuel catalysis, innovatively proposing a dual-path framework based on distinct electrical intervention mechanisms: Cross-Space Charge Transfer System and Local Electric Field Regulation System, elucidating their unique roles in bridging light absorption and fuel synthesis. In the former, the charge transfer driven by external bias enhances the separation of photogenerated charges in single photoelectrode photoelectrocatalysis (PEC), while the self-powered dual photoelectrodes PEC-PEC, photovoltaic-photoelectrocatalysis (PV-PEC), and photovoltaic-electrocatalysis (PV-EC) systems achieve zero energy conversion from solar energy to fuel through band matching and device integration, utilizing charge transfer driven by photogenerated potential.
View Article and Find Full Text PDFNat Nanotechnol
July 2025
National Laboratory of Solid State Microstructures, Jiangsu Key Laboratory of Artificial Functional Materials, College of Engineering and Applied Sciences, Nanjing University, Nanjing, People's Republic of China.
Ferroelectric topological textures in oxides exhibit exotic dipole-moment configurations that would be ideal for nonlinear spatial light field manipulation. However, conventional ferroelectric polar topologies are spatially confined to the nanoscale, resulting in a substantial size mismatch with laser modes. Here we report a dome-shaped ferroelectric topology with micrometre-scale lateral dimensions using nanometre-thick freestanding BaTiO membranes and demonstrate its feasibility for spatial light field manipulation.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia.
Earth-abundant metal oxides are excellent candidates for photocatalytic applications due to their low cost and high stability in aqueous solutions. Materials that contain a combination of metal cations with an electron lone pair and a electronic configuration, such as BiVO, possess favorable band gaps. BiVO has also been reported to possess noncentrosymmetric polar properties, such as flexoelectricity, piezo-photocatalysis, and an anomalous photovoltaic effect, despite its centrosymmetric crystal structure.
View Article and Find Full Text PDFNat Commun
October 2024
National Laboratory of Solid State Microstructures, Jiangsu Key Laboratory of Artificial Functional Materials, College of Engineering and Applied Sciences, Nanjing University, Nanjing, P. R. China.
Van der Waals integration of freestanding perovskite-oxide membranes with two-dimensional semiconductors has emerged as a promising strategy for developing high-performance electronics, such as field-effect transistors. In these innovative field-effect transistors, the oxide membranes have primarily functioned as dielectric layers, yet their great potential for structural tunability remains largely untapped. Free of epitaxial constraints by the substrate, these freestanding membranes exhibit remarkable structural tunability, providing a unique material system to achieve huge strain gradients and pronounced flexoelectric effects.
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