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Manure containing antibiotics is considered a hazardous substance that poses a serious health risk to the environment and to human health. Anaerobic digestion (AD) could not only treatment animal waste but also generate valuable biogas. However, the interaction between antibiotics in manure and the AD process has not been clearly understood. In this study, experiments on biochemical methane potential (BMP) were conducted to determine the inhibition of the AD process from antibiotics and the threshold of complete antibiotic removal. The thresholds of the complete antibiotic removal were 60 and 40mg/kg·TS for CTC and OTC, respectively. CTC and OTC with concentrations below thresholds could increase the BMP of manure. When the CTC and OTC concentrations exceeded the thresholds, they inhibited manure fermentation, and the CTC removal rate declined exponentially with concentration (60-500mg/kg·TS). The relationship between OTC antibiotic concentration and its removal rate in AD treatment was described with exponential (40-100mg/kg·TS) and linear equations (100-500mg/kg·TS).
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http://dx.doi.org/10.1016/j.wasman.2016.07.020 | DOI Listing |
Environ Res
August 2025
Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecu
The persistent presence of tetracycline antibiotics such as chlortetracycline (CTC) and oxytetracycline (OTC) in aquatic environments has emerged as a critical environmental concern. To address this challenge, we developed a novel composite adsorbent through strategic doping of bismuth into the HKUST-1 metal-organic framework (MOF), followed by encapsulation within a copper alginate (SA-Cu) hydrogel matrix. This innovative synthesis protocol yielded BiHKUST-1/SA-Cu, which was characterized using SEM, XRD, FT-IR, and XPS to elucidate its structural and chemical properties.
View Article and Find Full Text PDFAnal Methods
August 2025
School of Pharmacy, Hebei Medical University, Shijiazhuang 050017, People's Republic of China.
Tetracycline antibiotic residue in food is of vital significance for public health. Hexagonal boron nitride (h-BN)-based materials are excellent absorbents for antibiotics, and modification of the h-BN surface would improve its adsorption ability. In this study, a FeO-modified h-BN nanocomposite (FeO@h-BN) was fabricated by a simple one-step coprecipitation method.
View Article and Find Full Text PDFMikrochim Acta
July 2025
Departamento de Química Analítica, Instituto Químico Para La Energía y El Medioambiente (IQUEMA), Universidad de Córdoba, Edificio Anexo "Marie Curie", Campus de Rabanales, 14071, Córdoba, Spain.
A microfluidic analytical system based on magnetically retained nanomaterials has been developed using fluorometric detection. This system utilizes magnetic gold nanoclusters (AuMNCs) to determine total tetracyclines using three of them as model-chlortetracycline (CTC), doxycycline (DC), and oxytetracycline (OTC)-in water samples by monitoring the change in the luminescent signal produced upon interaction. AuMNCs were synthesized by adding preformed magnetic nanoparticles (MNPs) to bovine serum albumin (BSA) as stabilizer and ascorbic acid as a reducing agent.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2026
School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, PR China.
Mesoporous SBA-15 silica was used as the carrier of 1,8-naphthalimide fluorophore and layered double hydroxides (LDHs), to construct a bifunctional composite material (LDH@NA-SBA) for the adsorption and sensing of tetracycline antibiotics (TCs). LDHs dispersed on SBA-15 overcame the shortcomings of easy agglomeration and improved the adsorption capacity. The adsorption of TCs on LDH@NA-SBA occurred due to electrostatic interaction, π-π stacking, hydrogen bonding and complexation.
View Article and Find Full Text PDFSci Rep
July 2025
Institute of Environment, Resource, Soil and Fertilizer, Zhejiang Academy of Agricultural Sciences, Hangzhou, 310021, People's Republic of China.
This study assessed the integration of housefly larva bioconversion with aerobic composting for chicken manure (MC) over a 45-day period (4 days of larval bioconversion + 41 days of aerobic composting) and compared it with direct composting (CK1) and sawdust-amended composting (CK2). Larval activity enhanced moisture reduction and substrate porosity, yielding 6.08% (w/w) maggot protein and reducing nutrient losses of C, N, P, and K by 13.
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