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Self-sorting regioisomers through the hierarchical organization of hydrogen-bonded rosettes. | LitMetric

Self-sorting regioisomers through the hierarchical organization of hydrogen-bonded rosettes.

Chem Commun (Camb)

Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.

Published: July 2016


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Article Abstract

The self-assembly of two regioisomeric hydrogen-bonding naphthalenes was studied in mixed states in different polarity solvents. The regioisomers co-assemble to form heteromeric rosettes in chloroform. Upon injecting this solution into methylcyclohexane the heteromeric rosettes kinetically form amorphous aggregates, which over time differentiate into thermodynamically stable distinct nanostructures through self-sorting.

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Source
http://dx.doi.org/10.1039/c6cc03419eDOI Listing

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