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The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.
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http://dx.doi.org/10.1039/c5cc04317d | DOI Listing |
Nat Commun
February 2019
Empa, Swiss Federal Laboratories for Material Science and Technology, 8600, Dübendorf, Switzerland.
Chem Commun (Camb)
August 2015
Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy.
The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.
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