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In this paper, we present: (i) a novel analog silicon retina featuring auto-adaptive pixels that obey the Michaelis-Menten law, i.e. V=V(m) I(n)/I(n)+σ(n); (ii) a method of characterizing silicon retinas, which makes it possible to accurately assess the pixels' response to transient luminous changes in a ±3-decade range, as well as changes in the initial steady-state intensity in a 7-decade range. The novel pixel, called M(2)APix, which stands for Michaelis-Menten Auto-Adaptive Pixel, can auto-adapt in a 7-decade range and responds appropriately to step changes up to ±3 decades in size without causing any saturation of the Very Large Scale Integration (VLSI) transistors. Thanks to the intrinsic properties of the Michaelis-Menten equation, the pixel output always remains within a constant limited voltage range. The range of the Analog to Digital Converter (ADC) was therefore adjusted so as to obtain a Least Significant Bit (LSB) voltage of 2.35mV and an effective resolution of about 9 bits. The results presented here show that the M(2)APix produced a quasi-linear contrast response once it had adapted to the average luminosity. Differently to what occurs in its biological counterparts, neither the sensitivity to changes in light nor the contrast response of the M(2)APix depend on the mean luminosity (i.e. the ambient lighting conditions). Lastly, a full comparison between the M(2)APix and the Delbrück auto-adaptive pixel is provided.
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http://dx.doi.org/10.1364/OE.23.005614 | DOI Listing |
Inorg Chem
September 2025
Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Key Laboratory of Light Energy Conversion Materials of Hunan Province College, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, P. R. China.
The super bulky sodium phosphanide, NaP(SiPr), was reacted with amidinatotetrylenes LECl (L = PhC(NBu), E = Si, Ge), resulting in the formation of phosphasilene LSi(SiPr) = PSiPr () and phosphanido germylene LGeP(SiPr) (), respectively. Investigation on the reactivity of and toward elemental sulfur was carried out, where a stepwise reaction yielding the silanethione LSi(=S)SiPr () and the silicon thioester analogue LSi(=S)SSiPr () was observed in the case of , while the treatment of with sulfur exclusively afforded the germanium thioester analogue. In addition, the reactions of with Fe(CO) and GeCl·1,4-dioxane led to the germylene-coordinated iron carbonyl and the asymmetric Ge-Ge-bonded complex, respectively, exhibiting the reactivity of the lone pair as well as a weak Ge-P bond.
View Article and Find Full Text PDFJ Phys Chem A
September 2025
Department of Chemistry, Xinzhou Normal University, 1 East Dunqi Street, Xinzhou 034000, Shanxi, People's Republic of China.
This work introduces the novel anionic cluster BSiZn as the smallest molecular "compass", featuring a unique two-layered architecture with a planar pentacoordinate boron (ppB) center. The cluster comprises a quasi-planar BSi stator─a silicon-based analogue of borozene with σ/π double aromaticity (6π + 10σ delocalized electrons)─and a Zn rotor dimer. High-level calculations (CCSD(T)//PBE0-D3) reveal an ultralow rotational barrier of 0.
View Article and Find Full Text PDFGels
August 2025
Institute of Food Science, Technology and Nutrition (ICTAN-CSIC), 28040 Madrid, Spain.
This study examines the effects of an emulsion gel (EG) and a fat bulking agent (BA), both formulated with pork lard (PL) and an alginate-based gelling system, as animal fat replacers in the reformulation of reduced-fat fresh pork sausages. Both fat analogs were characterized in terms of texture, color, and in vitro gastrointestinal digestion (GID) before being used in the reformulation of four fresh pork sausages, without and with added silicon (Si) from diatomaceous earth powder: S/EG, S/EG-Si, S/BA, and S/BA-Si. Reduced-fat sausages elaborated exclusively with pork backfat (PB), without and with Si, were used as controls (S/C and S/C-Si).
View Article and Find Full Text PDFBiomedicines
August 2025
IRCCS San Raffaele Roma, Via della Pisana 235, 00163 Rome, Italy.
: Despite its central role in pediatric pre-surgical evaluation of drug-resistant focal epilepsy, conventional analog F-fluorodeoxyglucose (F-FDG) PET/CT (aPET) systems often yield modest epileptogenic zone (EZ) detection rates (~50-60%). Silicon photomultiplier-based digital PET/CT (dPET) promises enhanced image quality, but its performance in pediatric epilepsy remains untested. : We retrospectively analyzed 22 children (mean age 11.
View Article and Find Full Text PDFBMC Plant Biol
August 2025
School of Agricultural and Veterinary Sciences, São Paulo State University (UNESP), Via de Acesso Prof. Paulo Donato Castellane, N.O.S., Jaboticabal, 14884900, Brazil.
Background: Glyphosate is widely used in citrus production, but its overuse can cause oxidative stress and reduced growth in young orange trees. Silicon (Si), a beneficial element, strengthens antioxidant defense pathways and attenuates oxidative damage. However, its role in alleviating glyphosate-induced stress, particularly through the non-enzymatic antioxidant systems, remains unclear.
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