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Article Abstract
A reaction sequence involving the 1,6-conjugate addition of a nucleophile to a dienyl diketone followed by Nazarov cyclization is described. Several nucleophiles are identified as competent initiators for the sequence. A different reaction outcome is observed when catalytic amounts of nucleophile are employed, involving elimination of the nucleophile after the electrocyclization.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3178270 | PMC |
| http://dx.doi.org/10.1021/ja205440x | DOI Listing |
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